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Sedimentation Potential and Velocity in a Concentrated Suspension of Soft Particles

โœ Scribed by Hiroyuki Ohshima


Publisher
Elsevier Science
Year
2000
Tongue
English
Weight
111 KB
Volume
229
Category
Article
ISSN
0021-9797

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โœฆ Synopsis


A theory of sedimentation in a concentrated suspension of spherical soft particles (i.e., polyelectrolyte-coated particles) is developed to obtain general expressions for sedimentation velocity of soft particles and sedimentation potential in the suspension. An Onsager relation between sedimentation potential and electrophoretic mobility of spherical soft particles in concentrated suspensions is derived for the case of low potentials and nonoverlapping electrical double layers of adjacent particles. Copyright 2000 Academic Press.


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Sedimentation Potential in a Concentrate
โœ Hiroyuki Ohshima ๐Ÿ“‚ Article ๐Ÿ“… 1998 ๐Ÿ› Elsevier Science ๐ŸŒ English โš– 199 KB

A theory of sedimentation in a concentrated suspension of spherical colloidal particles proposed by Levine et al. (J. Colloid Interface Sci. 57, 424 (1976)) is further developed to derive a simple convenient expression for the sedimentation potential applicable for low zeta potentials and nonoverlap

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In this paper the theory of the sedimentation velocity and potential (gradient) in a dilute suspension of charged spherical colloidal particles developed by Ohshima et al. (H. Ohshima, T. W. Healy, L. R. White, and R. W. O'Brien, J. Chem. Soc., Faraday Trans. 2, 80, 1299 (1984)) has been modified to

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A general theory is developed for the electrophoretic mobility of spherical soft particles (i.e., spherical hard colloidal particles of radius a coated with a layer of polyelectrolytes of thickness d) in concentrated suspensions in an electrolyte solution as a function of the particle volume fractio