A theory of sedimentation in a concentrated suspension of spherical colloidal particles proposed by Levine et al. (J. Colloid Interface Sci. 57, 424 (1976)) is further developed to derive a simple convenient expression for the sedimentation potential applicable for low zeta potentials and nonoverlap
Sedimentation Potential and Velocity in a Concentrated Suspension of Soft Particles
โ Scribed by Hiroyuki Ohshima
- Publisher
- Elsevier Science
- Year
- 2000
- Tongue
- English
- Weight
- 111 KB
- Volume
- 229
- Category
- Article
- ISSN
- 0021-9797
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โฆ Synopsis
A theory of sedimentation in a concentrated suspension of spherical soft particles (i.e., polyelectrolyte-coated particles) is developed to obtain general expressions for sedimentation velocity of soft particles and sedimentation potential in the suspension. An Onsager relation between sedimentation potential and electrophoretic mobility of spherical soft particles in concentrated suspensions is derived for the case of low potentials and nonoverlapping electrical double layers of adjacent particles. Copyright 2000 Academic Press.
๐ SIMILAR VOLUMES
A general expression for the electrical conductivity of a concentrated suspension of spherical soft particles (polyelectrolyte-coated particles) is obtained for the case where the overlapping of the electrical double layers of adjacent particles is negligible by using Kuwabara's cell model. It is sh
Body-force-driven migration in a homogeneous suspension of spherical charge-regulating particles with electrical double layers of arbitrary thickness is analyzed. The charge regulation due to association/dissociation reactions of functional groups on the particle surface is approximated by a lineari
In this paper the theory of the sedimentation velocity and potential (gradient) in a dilute suspension of charged spherical colloidal particles developed by Ohshima et al. (H. Ohshima, T. W. Healy, L. R. White, and R. W. O'Brien, J. Chem. Soc., Faraday Trans. 2, 80, 1299 (1984)) has been modified to
A general theory is developed for the electrophoretic mobility of spherical soft particles (i.e., spherical hard colloidal particles of radius a coated with a layer of polyelectrolytes of thickness d) in concentrated suspensions in an electrolyte solution as a function of the particle volume fractio