Secondary α-Deuterium Kinetic Isotope Effects: Assumptions Simplifying Interpretations of Mechanisms of Solvolyses of Secondary Alkyl Sulfonates
✍ Scribed by Bentley, T. William
- Book ID
- 126029719
- Publisher
- American Chemical Society
- Year
- 2004
- Tongue
- English
- Weight
- 63 KB
- Volume
- 69
- Category
- Article
- ISSN
- 0022-3263
No coin nor oath required. For personal study only.
📜 SIMILAR VOLUMES
The mechanism of the Diels-Alder reaction has received much attention recently. ## 2-6 The question of whether formation, isomerization, or decomposition of Dielsdlder adducts occur via a one step 2,5 or a two step3'4'6 mechanism, has been asked most frequently. The use of the secondary adeuteriu
Sumnary: Addition of phenyl radical to benzyl isocyanides gives benzonitrile and benzyl radicals, exhibiting positive Hamnett p=O.26 and notable secondary a-deuterium kinetic isotope effects. These can be rationalized by concerted bond formation/cleavage occurring with polar transition states(TS).