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The Secondary α-Deuterium Isotope Effect: The Mechanism of the Thermal Decomposition of Azo-bis-α-phenylethane 1

✍ Scribed by Seltzer, Stanley

Book ID
127283982
Publisher
American Chemical Society
Year
1961
Tongue
English
Weight
624 KB
Volume
83
Category
Article
ISSN
0002-7863

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The secondary α-deuterium isotope effect
The secondary α-deuterium isotope effect and the mechanism of the diels-alder reaction
✍ Stanley Seltzer 📂 Article 📅 1962 🏛 Elsevier Science 🌐 French ⚖ 203 KB

The mechanism of the Diels-Alder reaction has received much attention recently. ## 2-6 The question of whether formation, isomerization, or decomposition of Dielsdlder adducts occur via a one step 2,5 or a two step3'4'6 mechanism, has been asked most frequently. The use of the secondary adeuteriu