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Secondary Isotope Effect in the Phosphorylase Reaction

โœ Scribed by Leonid M. Firsov; Tatjana I. Bogacheva; Simeon E. Bresler


Book ID
115114061
Publisher
John Wiley and Sons
Year
1974
Tongue
English
Weight
512 KB
Volume
42
Category
Article
ISSN
1432-1327

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Chorismate synthase (EC 4.6.1.4) is the shikimate pathway enzyme that catalyzes the conversion of 5-enolpyruvylshikimate 3-phosphate (EPSP) to chorismate. The enzyme reaction is unusual because it involves a trans-1,4 elimination of the C-3 phosphate and the C-6 proR hydrogen and it has an absolute