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The Secondary Deuterium Isotope Effect on the Diels-Alder Reaction

✍ Scribed by Van Sickle, Dale E.; Rodin, J. Otto.


Book ID
126126547
Publisher
American Chemical Society
Year
1964
Tongue
English
Weight
557 KB
Volume
86
Category
Article
ISSN
0002-7863

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The secondary Ξ±-deuterium isotope effect
✍ Stanley Seltzer πŸ“‚ Article πŸ“… 1962 πŸ› Elsevier Science 🌐 French βš– 203 KB

The mechanism of the Diels-Alder reaction has received much attention recently. ## 2-6 The question of whether formation, isomerization, or decomposition of Dielsdlder adducts occur via a one step 2,5 or a two step3'4'6 mechanism, has been asked most frequently. The use of the secondary adeuteriu