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Secondary effect on barriers to rotation in substituted ethanes

โœ Scribed by Anderson, J. E.; Pearson, H.

Book ID
127059226
Publisher
American Chemical Society
Year
1975
Tongue
English
Weight
730 KB
Volume
97
Category
Article
ISSN
0002-7863

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๐Ÿ“œ SIMILAR VOLUMES

The effect of halogen atoms in barriers
The effect of halogen atoms in barriers to rotation in substituted ethanes
โœ J.E. Anderson; H. Pearson ๐Ÿ“‚ Article ๐Ÿ“… 1972 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 88 KB

There have been reports recently on the effect of alkyl groups on barriers to rotation in highly substituted ethanes 2a-d ; we here report the effect of halogen atoms. The Table shows rate constants and

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Distortional effects on the ethane inter
Distortional effects on the ethane internal rotation barrier and rotation barriers in borazane and methylsilane
โœ A. Veillard ๐Ÿ“‚ Article ๐Ÿ“… 1969 ๐Ÿ› Elsevier Science ๐ŸŒ English โš– 326 KB

Receised 7 February -969 Distortional effects on the barrier to L?p?nal rotation of ethane x-e investigated through ab tnttto calculations. yielding a theoretical barrier of 3.071 kcal/mole (experimental 2.928 kcal/mole). The com-Lwted barrier is 3.064 kcal/moIe ior borazane and 1.44 kcal/mole for m