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Second sphere coordination in anion binding: Synthesis, characterization and X-ray structure of cis-diazidobis(ethylenediamine)cobalt(III) mesitylenesulphonate hemihydrate

✍ Scribed by Raj Pal Sharma; Rajni Sharma; Ritu Bala; Kamal Nain Singh; Loretta Pretto; Valeria Ferretti

Publisher
Elsevier Science
Year
2006
Tongue
English
Weight
476 KB
Volume
784
Category
Article
ISSN
0022-2860

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Second sphere coordination in anion bind
Second sphere coordination in anion binding: Synthesis, characterization and X-ray structure of [cis-diazidobis(ethylenediamine)cobalt(III)][trans-diamminetetranitrocobaltate(III)]
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Dark maroon coloured single crystals of [cis-Co(en)2(N3)2][trans-Co(NH3)2(NO2)4] were obtained by slowly mixing the separately dissolved [cis-diazidobis(ethylenediamine)cobalt(III)] nitrate with potassium [trans-diamminetetranitrocobaltate(III)] in aqueous medium in 1:1 molar ratio. The complex salt

Second Sphere Coordination in Anion Bind
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