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Second order interference effects in the fundamental band spectra of HCl and DCl in liquid Xe

✍ Scribed by A. Padilla; J. Pe´rez

Book ID
104304155
Publisher
Elsevier Science
Year
2000
Tongue
English
Weight
696 KB
Volume
84
Category
Article
ISSN
0167-7322

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✦ Synopsis

Second order interference effects have been incorporated in the calculation of the quasifree rotation absorption coefficient of diatomic molecules in non polar solvents. These effects are analysed in the calculation of the ftmdamental band infrared spectra of HCI and DCl in liquid Xe at T = 205 K , and the results are compared with the experhnental data of Knudtson and Weitz [J. Chem. Phys. 83, 927 (1985)]. Second order interference effects show relevant contributions both in the spectral regions near to the maximum of the P and R branches, and in the PR inter-braur, h region.

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