[(SeCl)2][FeCl4]: Synthesis, Quantumchemical Calculations, Vibrational Data and Single-Crystal X-ray Structure
✍ Scribed by Broschag, Matthias ;Klapätke, Thomas M. ;Schulz, Axel ;White, Peter S.
- Publisher
- Wiley (John Wiley & Sons)
- Year
- 1994
- Tongue
- English
- Weight
- 268 KB
- Volume
- 127
- Category
- Article
- ISSN
- 0009-2940
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## Abstract For Abstract see ChemInform Abstract in Full Text.
A hydrothermal reaction of NaVO 3 , H 3 BO 3 , Zn(CH 3 COO) 2 , ethylenediamine, and H 2 O gives a coordination cluster [Zn(en (denoted on Zn 6 V 12 B 18 ). The Zn 6 V 12 B 18 crystallizes in a rhombohedral system with space group R-3 and unit cell parameters a ؍ 20.686(3) A s , c ؍ 20.915(4) A
Two new compounds, Rb 2 (HSO 4 )(H 2 PO 4 ) and Rb 4 (HSO 4 ) 3 (H 2 PO 4 ), were synthesized from aqueous solutions of RbHSO 4 /RbH 2 PO 4 . The compounds were characterized by Xray single crystal analysis and neutron powder di4raction. For Rb 2 (HSO 4 )(H 2 PO 4 ), room temperature and a low tempe