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Search for the possible intermediacy of a 1,4-bishomotropylium ion in solvolysis

✍ Scribed by D. Cook; A. Diaz; J.P. Dirlam; D.L. Harris; M. Sakai; S. Winstein; J.C. Barborak; P.von R. Schleyer

Publisher
Elsevier Science
Year
1971
Tongue
French
Weight
195 KB
Volume
12
Category
Article
ISSN
0040-4039

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✦ Synopsis

A cation, assigned the bridged l,k-bishomotropylium structure I (R=H): ha8 been generated in superacid medium from several precursors: bicyclo[3.2.2]nonatrienol (II) (2 the barbaralyl cation (111)2), exo-7-hydroxy-cis-bicyclo[k.j.O]nonatriene (ZCV'-OH),~ and exo-J-hydroxytricyclo ---C4.3.0.02'S]nona-4,7-diene (V-OH).3

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