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(Se4)2[Mo2O2Cl8] [MCl6] (M: Zr Hf) — Tetraselenium(2+)Halometalates with Two Different Anions.

✍ Scribed by Johannes Beck; Matthias Kellner; Matthias Kreuzinger

Publisher
John Wiley and Sons
Year
2003
Weight
67 KB
Volume
34
Category
Article
ISSN
0931-7597

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Compounds with Cluster Cations together
Compounds with Cluster Cations together with Cluster Anions [(M6X12)(EtOH)6]2+ besides [(Mo6Cl8)Cl4X2]2– (M = Nb, Ta; X = Cl, Br) – Synthesis and Crystal Structures
✍ I. Bašic; N. Brničević; U. Beck; A. Simon; R. E. McCarley 📂 Article 📅 1998 🏛 John Wiley and Sons 🌐 German ⚖ 179 KB 👁 1 views

Compounds consisting of both cluster cations and cluster anions of the composition [(M 6 X 12 )(EtOH) 6 ][(Mo 6 Cl 8 )Cl 4 X 2 ] ´n EtOH ´m Et 2 O (M = Nb, Ta; X = Cl, Br) have been prepared by the reaction of (M 6 X 12 )X 2 ´6 EtOH with (Mo 6 Cl 8 )Cl 4 . IR data are given for three compounds. The