Screening of chiral ferrocenyl amino alcohols as ligands for ruthenium-catalysed transfer hydrogenation of ketones
β Scribed by Angela Patti; Sonia Pedotti
- Publisher
- Elsevier Science
- Year
- 2003
- Tongue
- English
- Weight
- 179 KB
- Volume
- 14
- Category
- Article
- ISSN
- 0957-4166
No coin nor oath required. For personal study only.
π SIMILAR VOLUMES
Some achiral b-amino alcohols have been shown as efficient ligands for the ruthenium-catalysed asymmetric transfer hydrogenation of N-(tert-butylsulfinyl)imines in isopropanol. The ruthenium complex prepared from [RuCl 2 (p-cymene)] 2 (2.5 mol %) and 2-amino-2-methyl-1-propanol (5 mol %) leads to a-
The nature of ruthenium-amino alcohol precursors in the aminoethane (1) coordinates through two nitrogen atoms, was structurally characterised by X-ray diffraction (8). -catalytic cycle of asymmetric hydrogen transfer reactions was studied using two C 2 -symmetrical tetradentate ligands (1 and Based