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Sc(OTf)3-catalyzed synthesis of pyrano[3,2-b]-1-benzopyrans from d-glycals

โœ Scribed by J.S Yadav; B.V.S Reddy; L Chandraiah; B Jagannadh; S.Kiran Kumar; Ajit C Kunwar


Publisher
Elsevier Science
Year
2002
Tongue
French
Weight
209 KB
Volume
43
Category
Article
ISSN
0040-4039

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โœฆ Synopsis


Glycals react smoothly with o-hydroxybenzaldehydes and trimethyl orthoformate in the presence of a catalytic amount of scandium triflate under mild reaction conditions to afford the corresponding cis-annelated pyranobenzopyrans in good yields with high diastereoselectivity.


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