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Schiff bases of pyridoxal and polyallylamine. The formation rate determining step

✍ Scribed by M. Angeles García Del Vado; Gerardo R. Echevarría Gorostidi; Andrea Basagoitía; José G. Santos Blanco; Francisco García Blanco

Publisher: John Wiley and Sons
Year: 1998
Tongue: English
Weight: 146 KB
Volume: 30
Category: Article
ISSN: 0538-8066
DOI: 10.1002/(sici)1097-4601(1998)30:1<1::aid-kin1>3.0.co;2-w

No coin nor oath required. For personal study only.

✦ Synopsis

The apparent rate constants of formation and hydrolysis of the Schiff

bases formed between pyridoxal and polyallylamine has been fitted to a kinetic scheme that involve the different protonated species in the reaction medium and the individual rate constants of formation (k and hydrolysis (k ). The (k ) values precludes an acid catalyzed

intramolecular process. The effects of hydrophobic medium due to the presence of the macromolecule on the reaction is also discussed.

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