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Scandium(III) oxide bromide, ScOBr

✍ Scribed by Jongen, Liesbet ;Meyer, Gerd

Book ID
104484558
Publisher
International Union of Crystallography
Year
2005
Tongue
English
Weight
110 KB
Volume
61
Category
Article
ISSN
1600-5368

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✦ Synopsis

Single crystals of scandium oxide bromide, ScOBr, were obtained as a by-product of the reaction of scandium tribromide, ScBr 3 , and scandium metal in a sealed tantalum container. ScOBr crystallizes with the FeOCl structure type. Br 1=2 Sc 1=2 OSc 1=2 Br 1=2 slabs are stacked in the direction of the c axis. Sc 3+ is surrounded in a distorted octahedral fashion according to the Niggli notation ScO 4=4 Br 2=2 .

πŸ“œ SIMILAR VOLUMES

Lutetium(III) oxide bromide, LuOBr
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✍ Zimmermann, Sina ;Pantenburg, Ingo ;Meyer, Gerd πŸ“‚ Article πŸ“… 2007 πŸ› International Union of Crystallography 🌐 English βš– 636 KB

Single crystals of lutetium oxide bromide, LuOBr, were obtained accidentally as a by-product of the reaction of lutetium metal, ruthenium powder and lutetium tribromide, LuBr 3 , in a sealed tantalum container. As is typical for rareearth oxide halides of the type REOX (RE = rare-earth metal and X =

Formation of scandium(III) chlorate and
Formation of scandium(III) chlorate and scandium(III) bromate complexes in aqueous solution
✍ D.F.C. Morris; F.B. Haynes; P.A. Lewis; E.L. Short πŸ“‚ Article πŸ“… 1972 πŸ› Elsevier Science 🌐 English βš– 592 KB

Ahstract4toichiometric stability constants for the formation of scandium(II1) chlorate and scandium(III) bromate complexes have been measured at several temperatures by using a liquid cation exchanger. Relations between ligational enthalpy and entropy changes are discussed in COMCXiOn with the forma