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Lutetium(III) oxide bromide, LuOBr

✍ Scribed by Zimmermann, Sina ;Pantenburg, Ingo ;Meyer, Gerd

Book ID
104491207
Publisher
International Union of Crystallography
Year
2007
Tongue
English
Weight
636 KB
Volume
63
Category
Article
ISSN
1600-5368

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✦ Synopsis

Single crystals of lutetium oxide bromide, LuOBr, were obtained accidentally as a by-product of the reaction of lutetium metal, ruthenium powder and lutetium tribromide, LuBr 3 , in a sealed tantalum container. As is typical for rareearth oxide halides of the type REOX (RE = rare-earth metal and X = halogen), LuOBr crystallizes in the tetragonal PbFCl structure type (matlockite), where Lu, O and Br are situated on positions with 4mm, 4m2 and 4mm symmetry, respectively.

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