✦ LIBER ✦

Scalar dynamic nuclear polarization of protons in trifluoroacetic acid solutions

✍ Scribed by John N. Helbert; Edward H. Poindexter; Burkhard E. Wagner

Publisher: Elsevier Science
Year: 1977
Tongue: English
Weight: 286 KB
Volume: 52
Category: Article
ISSN: 0009-2614
DOI: 10.1016/0009-2614(77)80506-x

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✦ Synopsis

Strongly scalar 'H intermolecular dynamic nuclear polarization (DNP) of solvent 'H nuclei in solutions of organic free radicals has now been observed at room temperature. Transient protonation of the CFaCOOHIpyridyl imidazoline-l-oxyl radical system accounts for the observed effects.

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