Sandwiched Ruthenium/Carbon Nanostructures for Highly Active Heterogeneous Hydrogenation
✍ Scribed by F. Su; F. Y. Lee; L. Lv; J. Liu; X. N. Tian; X. S. Zhao
- Publisher
- John Wiley and Sons
- Year
- 2007
- Tongue
- English
- Weight
- 407 KB
- Volume
- 17
- Category
- Article
- ISSN
- 1616-301X
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The hydrogenation of benzene and benzene derivatives was studied using Ru(0) nanoparticles prepared by a very simple method based on the in situ reduction of the commercially available precursor ruthenium dioxide under mild conditions (75 • C and hydrogen pressure 4 atm) in imidazolium ionic liquids
The application of the planar chiral [2.2]PHANEPHOS ligand in the Ru(II)-catalyzed asymmetric hydrogenation of ~ketoesters gave up to 96% ee involving a practical and reproducible procedure using the defined and readily prepared [2.2]PHANEPHOS-Ru(lI)bis(trifluoroacetate) salt in the presence of a ha