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Sandwich and Mixed Sandwich Complexes of the Cesium Ion with Crown Ethers in Nitromethane

✍ Scribed by Kim, Jineun; Shamsipur, Mojtaba; Huang, Song Z.; Huang, Rui H.; Dye, James L.

Book ID
120318259
Publisher
American Chemical Society
Year
1999
Tongue
English
Weight
77 KB
Volume
103
Category
Article
ISSN
1089-5639

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AbstractÐAmmonium nitrate coordinates to 18-crown-6 through a near-ideal `tripod' arrangement of hydrogen bonds to alternate crown ether oxygen atoms. Ion pairing interactions are apparent, with the strength of this ion pairing interaction appearing to be reduced by hydration, representing a potenti