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Salt effects on the reactivity and the stability of organomanganese reagents

✍ Scribed by Gérard Cahiez; Lynah Razafintsalama; Blandine Laboue; Francois Chau


Book ID
108386466
Publisher
Elsevier Science
Year
1998
Tongue
French
Weight
257 KB
Volume
39
Category
Article
ISSN
0040-4039

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A new synthetic route to organomanganese sulfonate reagents has been developed. These useful reagents can be readily prepared via direct oxidative addition of highly reactive manganese to carbon-oxygen bonds of the corresponding tosylates and mesylates under mild conditions.