A new synthetic protocol for the direct preparation of organomanganese reagents; organomanganese tosylates and mesylates

✍ Scribed by Seung-Hoi Kim; Reuben D. Rieke

• Publisher: Elsevier Science
• Year: 1999
• Tongue: French
• Weight: 205 KB
• Volume: 40
• Category: Article
• ISSN: 0040-4039
• DOI: 10.1016/s0040-4039(99)00861-8

✦ Synopsis

A new synthetic route to organomanganese sulfonate reagents has been developed. These useful reagents can be readily prepared via direct oxidative addition of highly reactive manganese to carbon-oxygen bonds of the corresponding tosylates and mesylates under mild conditions.