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Réactions des ions nitrate et acétate avec les sels de triphénoxy-méthyl-phosphonium

✍ Scribed by R. F. Hudson; P. A. Chopard

Publisher
John Wiley and Sons
Year
1962
Tongue
German
Weight
646 KB
Volume
45
Category
Article
ISSN
0018-019X

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✦ Synopsis

Abstract

The reaction between triphenyl‐methyl‐phosphonium iodide and silver acetate in acetonitrile gives diphenyl methylphosphonate and phenyl acetate. The corresponding reaction with silver nitrate gives the phosphonate and a mixture of o‐ and p‐nitrophenols. In the presence of an alcohol, the corresponding alkyl phenyl methylphosphonate is obtained. The mechanisms of these reactions are discussed in the light of the general reactions of quaternary phosphonium compounds.

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