Rydberg—valence mixing in atoms and molecules
✍ Scribed by William L. Luken
- Publisher
- Elsevier Science
- Year
- 1979
- Tongue
- English
- Weight
- 603 KB
- Volume
- 61
- Category
- Article
- ISSN
- 0009-2614
No coin nor oath required. For personal study only.
✦ Synopsis
Interactions of R> dbers ckctronic confipurations x\ith excited intravalenq configurations hate a large inftuence on atwnic sperm-a ;t+ owl! as molcr~br clscrronic spcctm_ The i I34 X resotmncc transition of the nitrogen atom is used to il-Iusrrste the pnagrrss x\hich has been achis\ed in Irating these effects in atoms. In addition, the fust-order theory of oscdlator strengths (I-OTOS) is>Rox\n to bean approGnation fo the non-clo~ed shell msn>-eIectron theory (SCWGT) of Sinzno~lu as zppliscx to osrdlator srrcn$hs.
📜 SIMILAR VOLUMES
Density effects and Ns co-doping of Kr solids doped with NO allow continuous tuning of the NO Rydberg state energies in a range 0.35 to 0.68 eV blue of the gas phase. This property is exploited to control the vibronic contiguration mixing between the Rydberg C \*II and the valence B \*lI states. The
A diagrammatic valence bond method based on Rumer-Pauling rules for configuration interaction calculations is described. The advantages of this method are that it is simple and flexible and is expected to be computationally efficient as the basis functions can be coded as increasing integers. Evalua
It is established that ionic terms have a great influence in 2Pl-z PA mixing in alkali atoms on colli- sions with diatomic molecules. Illustrating calculations were dohe a&l a cross section was obtained for the process.