✦ LIBER ✦
Control by density effects of the Rydberg-valence configuration mixing in matrix isolated NO
✍ Scribed by M. Chergui; R. Reininger; E. Morikawa; A. Tramer
- Publisher
- Elsevier Science
- Year
- 1993
- Tongue
- English
- Weight
- 679 KB
- Volume
- 216
- Category
- Article
- ISSN
- 0009-2614
No coin nor oath required. For personal study only.
✦ Synopsis
Density effects and Ns co-doping of Kr solids doped with NO allow continuous tuning of the NO Rydberg state energies in a range 0.35 to 0.68 eV blue of the gas phase. This property is exploited to control the vibronic contiguration mixing between the Rydberg C *II and the valence B *lI states. The influence on the interference lineshapes resulting from the interaction of discrete valence bands with the broad multiphonon Rydberg bands is discussed in terms of estimates of the Fano indices.