Rydberg states and quantum defects of the NO molecule
โ Scribed by Karl Kaufmann; Christoph Nager; Martin Jungen
- Publisher
- Elsevier Science
- Year
- 1985
- Tongue
- English
- Weight
- 589 KB
- Volume
- 95
- Category
- Article
- ISSN
- 0301-0104
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High-resolution laser specwoscopy was used IO study autotomzanon in the 4f complex 01 NO, \xIrh I = 3 Lkllmcs rangmg kom 37 IO 300 ps were measured. The 4f stale IS non-penetrallng and its autoionization is probably medrnk!d rl: leas1 in par1 by long-range interactions with Ihe NO+ core
A model for the dynamics of high Rydberg states in isolated large molecules is proposed. The model accounts for the interaction between the electron and the vibrational degrees of freedom of the core. These are modelled by an Ohmic bath in thermal equilibrium. A reduced-density-matrix description is