Fine structure in Rydberg states of the H2 molecule
β Scribed by A.Norman Jette; Terry A. Miller
- Publisher
- Elsevier Science
- Year
- 1974
- Tongue
- English
- Weight
- 623 KB
- Volume
- 29
- Category
- Article
- ISSN
- 0009-2614
No coin nor oath required. For personal study only.
π SIMILAR VOLUMES
We calculate oscillator strengths for Rydberg electron transitions in polar molecules with a simple analytical procedure of taking into account the effects of nonspherical symmetry of molecular core field due to its dipole moment. Such effects result in nonzero oscillator strengths values for some t
Theoretical calculations are presented on the vertical spectra of H2S as well as along bending and symmetric dissociation paths. The results show that interactions of the dissociating 'A, (5a,d6a, (4s)) state with the (%,-+a~, np, nd) Rydberg states might lead to predlssociation of the latter, for R
The absorpllon spectrum of HZ molecules m a NC muIrI\ m the energy range of I l-I,.-? 7 CV due the vibrational lcvcls u = 0.. ., 7 of the B ' xi+-X '1; Rydbcrg tr.msltlon IS reported
ab initio theoretical calculations on 32 excited states of Hz0 found to lie below 11.7 eV. Of the eight states observed experimentally, the svemge discrepancy between theoretical and esperimental excitation energies is 0.1 eV. We find that the excited states can each be characterized as arising from