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Ruthenium(VI)-Catalyzed Oxidation of Alcohols by Hexacyanoferrate(III): An Example of Mixed Order

✍ Scribed by Mucientes, Antonio E.; de la Peña, María A.

Book ID
120014617
Publisher
American Chemical Society
Year
2006
Tongue
English
Weight
88 KB
Volume
83
Category
Article
ISSN
0021-9584

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## Abstract The kinetics of the Ru(VI)‐catalyzed oxidation of benzyl alcohol by hexacyanoferrate(III), in an alkaline medium, has been studied using a spectrophotometric technique. The initial rates method was used for the kinetic analysis. The reaction is first order in [Ru(VI)], while the order c

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## Abstract The title reaction shows a mixed kinetic order with respect to hexacyanoferrate(III). The reaction tends to be single zero order at high [Fe(CN)] and single first order at low [Fe(CN)]. For this reason, the decay of the absorbance of hexacyanoferrate(III) at 420 nm changes from linear t