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Ruthenium(salen)-Catalyzed Aerobic Oxidative Desymmetrization of meso-Diols and Its Kinetics.

✍ Scribed by Hideki Shimizu; Satoaki Onitsuka; Hiromichi Egami; Tsutomu Katsuki


Publisher
John Wiley and Sons
Year
2005
Weight
41 KB
Volume
36
Category
Article
ISSN
0931-7597

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with respect to the catalyst concentration is first. The reaction mechanism supposes the formation of a complex between the substrate and the catalyst active form . Subsequently, the complex thus formed slowly decomposes in the rate determining step to give carbonium ions and ruthenium hydride, sinc