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Ruthenium(III)—Schiff base complex-catalyzed carbonylation of nitrobenzene to give phenylurethane

✍ Scribed by S.B. Halligudi; K.N. Bhatt; N.H. Khan; M.M.Taqui Khan


Publisher
Elsevier Science
Year
1992
Weight
261 KB
Volume
72
Category
Article
ISSN
0304-5102

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✍ K. J. Tony; V. Mahadevan; J. Rajaram; C. S. Swamy 📂 Article 📅 1996 🏛 John Wiley and Sons 🌐 English ⚖ 345 KB 👁 1 views

The Ru[lll) Schiff base complex, 1 Ru[ L)CI,ICI; L = Gis[picolinaldehyde) o-phenylenediimine. catalyzes the oxidation of secondary alcohols by N-methylrnorpholine-N-oxide( NMO) or thal-Iium(lll) acetate as oxidant, Kinetic studies showed the formation of R u ( V ) species as the active intermediate