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Ruthenium(III) chloride in aqueous solution: kinetics of the aquation and anation reactions of the chloro complexes

โœ Scribed by Khan, M. M. Taqui; Ramachandraiah, G.; Shukla, R. S.


Book ID
120233833
Publisher
American Chemical Society
Year
1988
Tongue
English
Weight
508 KB
Volume
27
Category
Article
ISSN
0020-1669

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The Co(NH3) 50Hz3+ ion reacts with malonate to form Co(NH3) 50~CCH2C02H2+ or Co(NH3) 50ZCCHzCOz+, depending on the pH of the reaction solution. The kinetics of this anation reaction have been studied as a function of [H+] for the acidity range 1.5 5 pH 5 6.0 in the temperature range of 60 to 8OoC, t