Ruthenium(III) acetylacetonate: A homogeneous catalyst in the hydrolysis of sodium borohydride
✍ Scribed by Ezgi Keçeli; Saim Özkar
- Publisher
- Elsevier Science
- Year
- 2008
- Tongue
- English
- Weight
- 414 KB
- Volume
- 286
- Category
- Article
- ISSN
- 1381-1169
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Over the past decade, sodium borohydride (NaBH 4 ) has been extensively investigated as a potential hydrogen storage material. The development of catalyst materials for on demand NaBH 4 hydrolysis, and the design of practical reaction systems for hydrogen storage based on NaBH 4 are key research are
The reduction of allyl aryl ethers using sodium borohydride in the presence of a catalytic amount of ruthenium(III) chloride in various aqueous solvent mixtures at 0 °C was examined. In aqueous tetrahydrofuran, hydrogenation was the favored pathway (85-100% yield of the corresponding aryl propyl eth