Osmium(II) and Ruthenium(II) Arene Malto
✍
Anna F. A. Peacock; Michael Melchart; Robert J. Deeth; Abraha Habtemariam; Simon
📂
Article
📅
2007
🏛
John Wiley and Sons
🌐
English
⚖ 475 KB
## Abstract Density functional calculations show that aquation of [Os(η^6^‐arene)(XY)Cl]^__n__+^ complexes is more facile for complexes in which XY=an anionic O,O‐chelated ligand compared to a neutral N,N‐chelated ligand, and the mechanism more dissociative in character. The O,O‐chelated XY=maltola