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Ruthenium(II) Complexes Containing Optically Active Hemilabile P,N,O-Tridentate Ligands. Synthesis and Evaluation in Catalytic Asymmetric Transfer Hydrogenation of Acetophenone by Propan-2-ol

✍ Scribed by Yang, Hong; Alvarez-Gressier, Marie; Lugan, Noël; Mathieu, René


Book ID
120416085
Publisher
American Chemical Society
Year
1997
Tongue
English
Weight
267 KB
Volume
16
Category
Article
ISSN
0276-7333

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Ruthenium(II) complexes of optically act
✍ Hong Yang; Noël Lugan; René Mathieu 📂 Article 📅 1999 🏛 Elsevier Science 🌐 English ⚖ 603 KB

The reaction of 2 equiv of the optically active P, N bidentate ligands l-3 with RuC1,(PPh,)3 gives the RuCl,(l-3)2 (4-6) complexes in good yield as a mixture of isomers. The solid state structure of RuC1,( 2), (SC) is described: the two chlorine atoms are in tram position and due to steric crowding,