Ruthenium(II) complexes of optically act
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Hong Yang; Noël Lugan; René Mathieu
📂
Article
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1999
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Elsevier Science
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English
⚖ 603 KB
The reaction of 2 equiv of the optically active P, N bidentate ligands l-3 with RuC1,(PPh,)3 gives the RuCl,(l-3)2 (4-6) complexes in good yield as a mixture of isomers. The solid state structure of RuC1,( 2), (SC) is described: the two chlorine atoms are in tram position and due to steric crowding,