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Ruthenium(II) catalyzed reaction of 1,4-epiperoxides

โœ Scribed by Suzuki, M.; Noyori, R.; Hamanaka, N.


Book ID
120284997
Publisher
American Chemical Society
Year
1982
Tongue
English
Weight
290 KB
Volume
104
Category
Article
ISSN
0002-7863

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Palladium(0) catalyzed reaction of 1,3-d
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Reaction of 1,3-diene 1,4-epiperoxides with Pd(PPh314 catalyst forms the corresponding 4-hydroxy enones, syn diepoxides, and 1,4-dials as the major products. The results are interpreted as being due to competing Pd(O)/Pd(II) and Pd(O)/Pd(I) exchange

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