Ruthenium-Catalyzed Transfer Hydrogenation of Nitriles: Reduction and Subsequent N -Monoalkylation to Secondary Amines
β Scribed by Werkmeister, Svenja; Bornschein, Christoph; Junge, Kathrin; Beller, Matthias
- Book ID
- 120268497
- Publisher
- John Wiley and Sons
- Year
- 2013
- Tongue
- English
- Weight
- 496 KB
- Volume
- 2013
- Category
- Article
- ISSN
- 1434-193X
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## Abstract RutheniumβΞ·βarene complexes attached to the secondary face of Ξ²βcyclodextrin catalyze the enantioselective reduction (__ee__ up to 98%) of aliphatic and aromatic ketones in aqueous medium in the presence of sodium formate (HCOONa).