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Ruthenium-Catalyzed Synthesis of 1,5-Dichlorides by Sequential Intermolecular Kharasch Reactions

✍ Scribed by Katrin Thommes; Mariano A. Fernández-Zúmel; Charlotte Buron; Aurélien Godinat; Rosario Scopelliti; Kay Severin


Publisher
John Wiley and Sons
Year
2010
Tongue
English
Weight
386 KB
Volume
2011
Category
Article
ISSN
1434-193X

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ChemInform Abstract: Ruthenium-Catalyzed
✍ Katrin Thommes; Mariano A. Fernandez-Zumel; Charlotte Buron; Aurelien Godinat; R 📂 Article 📅 2011 🏛 John Wiley and Sons ⚖ 36 KB

## Abstract Ruthenium‐catalyzed reaction of styrene derivatives (II) with α,α‐dichloro‐malononitrile, ‐malonate or ‐acetonitrile (I) proceeds via a double Kharasch pathway to give symmetrical or unsymmetrical 1,5‐diaryl‐1,5‐dichlorides in good yields.