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Ruthenium-catalyzed linear selective allylic aminations of monosubstituted allyl acetates

✍ Scribed by Motoi Kawatsura; Fumio Ata; Takuya Hirakawa; Shuichi Hayase; Toshiyuki Itoh

Publisher: Elsevier Science
Year: 2008
Tongue: French
Weight: 168 KB
Volume: 49
Category: Article
ISSN: 0040-4039
DOI: 10.1016/j.tetlet.2008.06.002

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✦ Synopsis

The ruthenium-catalyzed highly linear selective allylic amination of monosubstituted allylic acetates with secondary amines was developed. The regioselectivity was controlled by the Ru 3 (CO) 12 /2-DPPBA catalyst, and a linear-type aminated product was obtained as a single regioisomer.

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