## Abstract The waterโsoluble ruthenium(II) complexes [CpโฒRuX(PTA)~2~]Y and [CpRuCl(PPh~3~)(mPTA)]OTf (Cpโฒ = Cp, Cp\*, X = Cl and Y = nil; or X = MeCN and Y = PF~6~; PTA = 1,3,5โtriazaโ7โphosphaadamantane; mPTA = 1โmethylโ1,3,5โtriazaโ7โphosphaadamantane) were used as catalyst precursors for the hy
โฆ LIBER โฆ
Ruthenium-Catalyzed Hydrogenation of Bicarbonate in Water
โ Scribed by Christopher Federsel; Dr. Ralf Jackstell; Albert Boddien; Dr. Gabor Laurenczy; Prof. Matthias Beller
- Book ID
- 102129683
- Publisher
- Wiley (John Wiley & Sons)
- Year
- 2010
- Tongue
- English
- Weight
- 219 KB
- Volume
- 3
- Category
- Article
- ISSN
- 1864-5631
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โฆ Synopsis
Figure 2. Hydrogenation of sodium bicarbonate with 0.55 mmol [RuCl 2 -(benzene)] 2 with 2 equiv. dppm or dppe at 70 8C and 90 bar H 2 over 10 h in a nonstirred high-pressure sapphire NMR tube.
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