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Understanding the Role of Water in Aqueous Ruthenium-Catalyzed Transfer Hydrogenation of Ketones.

✍ Scribed by Anna Pavlova; Prof. Evert Jan Meijer


Book ID
115554797
Publisher
John Wiley and Sons
Year
2012
Tongue
English
Weight
1000 KB
Volume
13
Category
Article
ISSN
1439-4235

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Chiral amino amides for the ruthenium(II
✍ Jincheng Mao; Jun Guo πŸ“‚ Article πŸ“… 2010 πŸ› John Wiley and Sons 🌐 English βš– 119 KB πŸ‘ 2 views

## Abstract The chiral amino amide **3** was derived from L‐proline and used for the [RuCl~2~(__p__‐cymene)]~2~‐catalyzed asymmetric transfer hydrogenation of prochiral ketones performed in water. Moderate to good chemical selectivities (up to 95% yield) and enantioselectivities (up to 90% ee) were