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Ruthenium-Catalyzed Hydrogenation of Alkynylstannanes with Migration of the Stannyl Group

โœ Scribed by Shirakawa, Eiji; Morita, Ryotaro; Tsuchimoto, Teruhisa; Kawakami, Yusuke


Book ID
127032146
Publisher
American Chemical Society
Year
2004
Tongue
English
Weight
45 KB
Volume
126
Category
Article
ISSN
0002-7863

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โœ Raluca Aldea; Howard Alper ๐Ÿ“‚ Article ๐Ÿ“… 2010 ๐Ÿ› John Wiley and Sons โš– 36 KB ๐Ÿ‘ 1 views

Hydrogenation of the Carbonyl Group in ฮฑ-Ketoesters and ฮฑ-Ketoamides Catalyzed by Ruthenium Clay. -The ruthenium clay, prepared from montmorillonite K10, (3-chloropropyl)trimethoxysilane, KPPh 2 , and RuCl 3 โ€ขH 2 O (0.13 to 0.17 mmol Ru/g clay) catalyzes effectively the reduction of the ฮฑ-carbonyl