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Ruthenium-Catalyzed Formation of Aryl(diphenyl)phosphine Oxides by Reactions of Propargylic Alcohols with Diphenylphosphine Oxide

โœ Scribed by Onodera, Gen; Matsumoto, Hideyuki; Milton, Marilyn Daisy; Nishibayashi, Yoshiaki; Uemura, Sakae


Book ID
126254323
Publisher
American Chemical Society
Year
2005
Tongue
English
Weight
94 KB
Volume
7
Category
Article
ISSN
1523-7060

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Aromatic and alkyl alcohols were oxidized to the corresponding aldehydes or ketones at room temperature with high conversion and selectivity to the desired products of 100% using iodosylbenzene as oxidant catalyzed by ruthenium complexes Phen-Ru-Phen, Phen-Ru-Bipy, Phen-Ru-Quin, Quin-Ru-Quin and Bip