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Ruthenium-Catalyzed [1, n ]-Metallotropic Shift ( n = 3, 5) of Alkynyl Carbene Complex Intermediates

✍ Scribed by Ohe, Kouichi; Fujita, Michinobu; Matsumoto, Hideyuki; Tai, Yugo; Miki, Koji


Book ID
127294794
Publisher
American Chemical Society
Year
2006
Tongue
English
Weight
61 KB
Volume
128
Category
Article
ISSN
0002-7863

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## Abstract The N‐heterocyclic carbene‐catalyzed reaction of alkynyl aldehydes with 1,3‐keto esters or 1,3‐diketones has been studied. This protocol offers an entirely new, mild and atom‐economical access to highly functionalized 3,4‐dihydropyranones.