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Ruthenium-Catalyzed [1,n]-Metallotropic Shift (n = 3, 5) of Alkynyl Carbene Complex Intermediates.

✍ Scribed by Kouichi Ohe; Michinobu Fujita; Hideyuki Matsumoto; Yugo Tai; Koji Miki


Publisher
John Wiley and Sons
Year
2006
Weight
27 KB
Volume
37
Category
Article
ISSN
0931-7597

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## Abstract The N‐heterocyclic carbene‐catalyzed reaction of alkynyl aldehydes with 1,3‐keto esters or 1,3‐diketones has been studied. This protocol offers an entirely new, mild and atom‐economical access to highly functionalized 3,4‐dihydropyranones.