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Ruthenium-catalysed asymmetric hydrogenation with fluoroalkylated BINAP ligands in supercritical CO2

✍ Scribed by Yulai Hu; David J Birdsall; Alison M Stuart; Eric G Hope; Jianliang Xiao


Book ID
108211344
Publisher
Elsevier Science
Year
2004
Tongue
English
Weight
75 KB
Volume
219
Category
Article
ISSN
1381-1169

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A strong positive nonlinear effect (asymmetric amplification) hydrogenated product with 91% ee. The influence of temperature and hydrogen pressure on this effect are was found to take place during asymmetric hydrogenations using chiral atropisomeric diphosphane-ruthenium catalysts. presented. These