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Ruthenium carbonyl complexes in catalytic epoxidation of olefins co-catalyzed by isobutyl-aldehyde

✍ Scribed by P. Aguirre; S. Zolezzi; J. Parada; E. Bunel; S. A. Moya; R. Sariego


Publisher
John Wiley and Sons
Year
2006
Tongue
English
Weight
121 KB
Volume
20
Category
Article
ISSN
0268-2605

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Isomerization of Propargylic Alcohols in
✍ Victorio Cadierno; Sergio E. García-Garrido; José Gimeno 📂 Article 📅 2006 🏛 John Wiley and Sons 🌐 English ⚖ 180 KB

## Abstract The 16‐e^−^ (η^3^‐allyl)‐ruthenium(II) complex [Ru(η^3^‐2‐C~3~H~4~Me)(CO)(dppf)][SbF~6~] is an efficient catalyst for the regioselective isomerization of terminal propargylic alcohols HCCCR^1^R^2^(OH) into α,β‐unsaturated aldehydes R^1^R^2^CCHCHO or ketones R^3^R^4^CC(R^1^)COMe (if R