Ruthenium carbonyl carboxylate complexes with nitrogen-containing ligands III. Catalytic activity in hydrogenation
โ Scribed by Piero Frediani; Mario Bianchi; Antonella Salvini; Roberto Guarducci; Luciano C. Carluccio; Franco Piacenti
- Publisher
- Elsevier Science
- Year
- 1995
- Tongue
- English
- Weight
- 748 KB
- Volume
- 498
- Category
- Article
- ISSN
- 0022-328X
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## Abstract Bis(ethene) complexes of rhodium(I) and iridium(I) with 8โquinolylcyclopentadienyl ligands (Cp^Q^ and Cp^Q^\*) were oxidized by a photochemically induced reaction with chlorineโcontaining solvents or by treatment with iodine. Upon this oxidation, the quinoline ring rotates and the N don
## Abstract A new and safer methodology has been developed for the synthesis of bis(pyrazolโ1โyl)methane ligands (NN). Several ligands containing different phenyl groups on the central carbon atom have been obtained. Ruthenium derivatives of the type [Ru(arene)Cl(NN)]BPh~4~ (arene = benzene, __p__โ