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Homogeneous catalytic hydrogenation with ruthenium(II) complexes containing phosphine or arsine chelating ligands

✍ Scribed by Kyun-Il Na; Seong Huh; Kie-Moon Sung; Moo-Jin Jun

Publisher: Elsevier Science
Year: 1996
Tongue: English
Weight: 372 KB
Volume: 15
Category: Article
ISSN: 0277-5387
DOI: 10.1016/0277-5387(95)00430-0

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## Abstract A new and safer methodology has been developed for the synthesis of bis(pyrazol‐1‐yl)methane ligands (NN). Several ligands containing different phenyl groups on the central carbon atom have been obtained. Ruthenium derivatives of the type [Ru(arene)Cl(NN)]BPh~4~ (arene = benzene, __p__‐