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Ruthenium-99 Mössbauer spectra of some nitrido complexes of Ru(VI)

✍ Scribed by T.C. Gibb; R. Greatrex; N.N. Greenwood; R.H. Meinhold


Publisher
Elsevier Science
Year
1974
Tongue
English
Weight
514 KB
Volume
29
Category
Article
ISSN
0009-2614

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The 99Ru Mössbauer spectrum of β-RuCl3
✍ F.M. Dacosta; T.C. Gibb; R. Greatrex; N.N. Greenwood 📂 Article 📅 1975 🏛 Elsevier Science 🌐 English ⚖ 230 KB

The 99Ru nuclear quadrupole interaction in pRuC13 can be related to the large irigonal distortion at the ruthenium site. The ratio of the quadrupole moments has been determined to be Qe/Qg = +3.06 + 0.10, and it is confirmed that Qe and Qg arc both positive.