๐”– Bobbio Scriptorium
โœฆ   LIBER   โœฆ

Ru(salen)-catalyzed asymmetric sulfimidation and subsequent [2,3]sigmatropic rearrangement

โœ Scribed by Masakazu Murakami; Tatsuya Uchida; Bunnai Saito; Tsutomu Katsuki

Publisher
John Wiley and Sons
Year
2003
Tongue
English
Weight
135 KB
Volume
15
Category
Article
ISSN
0899-0042

No coin nor oath required. For personal study only.

๐Ÿ“œ SIMILAR VOLUMES

Chiral (OC)Ru(salen)-catalyzed tandem su
Chiral (OC)Ru(salen)-catalyzed tandem sulfimidation and [2,3]sigmatropic rearrangement: asymmetric C๎—ธN bond formation
โœ Masakazu Murakami; Tsutomu Katsuki ๐Ÿ“‚ Article ๐Ÿ“… 2002 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 67 KB

Asymmetric C N bond formation was achieved in a highly enantioselective manner by using (OC)Ru(salen)-catalyzed sulfimidation and the subsequent [2,3]sigmatropic rearrangement: treatment of allyl aryl sulfides with p-toluenesulfonyl azide in the presence of a catalytic amount of (OC)Ru(salen) follow

Catalytic and asymmetric [2,3]sigmatropi
Catalytic and asymmetric [2,3]sigmatropic rearrangement: Co(III)-salen catalyzed S-ylide formation from allyl aryl sulfides and their rearrangement
โœ Tsutomu Fukuda; Ryo Irie; Tsutomu Katsuki ๐Ÿ“‚ Article ๐Ÿ“… 1999 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 998 KB

Reaction of allyl aryl sulfides and a-diazoacetic acid esters in the presence of optically active Co(HD-salen complex (8-Br) provided 3-substituted 2-arylthio-4-pentenoic acid esters stereo~l~vely by way of enantioselcctive S-ylide formation and subse~luent diastereoselective [2,3]sismalropic rearra