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Chiral (OC)Ru(salen)-Catalyzed Tandem Sulfimidation and [2,3]Sigmatropic Rearrangement: Asymmetric C—N Bond Formation.

✍ Scribed by Masakazu Murakami; Tsutomu Katsuki


Publisher
John Wiley and Sons
Year
2010
Weight
35 KB
Volume
33
Category
Article
ISSN
0931-7597

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Chiral (OC)Ru(salen)-catalyzed tandem su
✍ Masakazu Murakami; Tsutomu Katsuki 📂 Article 📅 2002 🏛 Elsevier Science 🌐 French ⚖ 67 KB

Asymmetric C N bond formation was achieved in a highly enantioselective manner by using (OC)Ru(salen)-catalyzed sulfimidation and the subsequent [2,3]sigmatropic rearrangement: treatment of allyl aryl sulfides with p-toluenesulfonyl azide in the presence of a catalytic amount of (OC)Ru(salen) follow